Aldehydes and Ketones
MDCAT • Chemistry
266 MCQs — Click "Reveal" to see the correct answer
Build a test-
1Which of the following compound can be used for the separation of ethanal from the mixture of ethanal and ethanol
-
2Which of the following does not give aldol condensation
-
3For aldol condensation the conditions necessary
-
4
Which of the following will not give addition reaction with NaHSO3:
-
5Which of the following do not give aldol condensation reactions
-
6Cannizzaro's reaction is not given by
-
7Which of the following carbonyl compounds shows rapid reaction with sodium nitroprusside
-
8Formalin is % solution of formaldehyde in water
-
9
X and Y in this reaction are respectively:
-
10Acetaldehyde gives which salt by reacting with ammonical silver nitrate
-
11Which of the following carbonyl compound can give aliphatic, saturated alcohol using NaBH4
-
12Strongest reducing agent that can reduce the Tollen's reagent is
-
13An aldehyde when boiled with Fehling solution gives brick red precipitate, red colour is due to
-
14
Which one of the following set of compounds oxidize aldehydes as well as ketones
-
15Which substance does not oxidize easily
-
16For which one of the following pairs of compounds can be distinguished by means of Tollen's tests.
-
17Catalytic reduction of acetone will produce
-
18
Reducing agent which attack carbonyl compound in NaBH4 is:
-
19Formation of eyanohydrin from an aldehyde is an example of
-
20
the X will be?
-
21Which of the following has maximum reactivity in nucleophilic addition reactions?
-
22
What will be the product in following reaction? CH₃CH = CHCH2 COCH₃ (in presence of NaBH4) ?
-
23Addition cyanide forms of HCN to acetaldehyde in the presence of dilute mineral acid and sodium
-
24
The reduction of a ketone using NaBH4 gives:
-
25Formation of yellow or orange/red precipitates with 2, 4-DNPH refers to the identification of
-
26Isobutyl alcohol on oxidation converts to a earbonyl compound A. A is
-
27Acetaldehyde is purified by which method when prepared by alcohol in laboratory
-
28
?
-
29
Which of the following is true regarding oxidation of an ethanol to an ethanal:
-
30Acidified sodium dichromate oxidizes ethanol to ethanal by producing
-
31Formaldehyde is prepared by passing and air over platinized asbestos catalyst at 300°C
-
32Formation of acetaldehyde by ethanol is known as
-
33Which of the following compound is oxidized to get methyl ethyl ketone
-
34Which of the following can be used for the oxidative preparation of aldehydes from alcohols
-
35Which one is aldehyde
-
36Which of the following is unsymmetrical ketone
-
37planar geometry is associated with
-
38Which of the following is correct statement regarding carbonyl compounds
-
39In carbonyl compounds carbonyl carbon is bonded to
-
40Carbonyl group is bonded to in ketones
-
41Strong oxidizing agents are required for oxidation of
-
42One mole of ethanol on oxidation gives
-
43
Reduction of propanone with NaBH₄/H3O+ gives
-
44Base catalyst increases character of
-
45Which of the following is more reactive?
-
46Which type of reactions are given by carbonyl compound?
-
47
Formalin incudes as well
-
48Dry distillation of Calcium salt of acetic acid gives
-
49is a symmetrical ketone
-
50
Empirical formula for methanal is
-
51UHS MDCAT 2008
Which of the following is used to make chloral hydrate?
-
52UHS MDCAT 2008
Aldehydes can be synthesized by the oxidation of:
-
53UHS MDCAT 2009
Which of the following compounds will react with Tollen's Reagent?
-
54UHS MDCAT 2009
When acetone is heated in the presence of K2Cr2O7/H2SO4, the products formed are:
-
55UHS MDCAT 2009
In the conversion of ethylene into acetaldehyde, cupric chloride acts as:
-
56UHS MDCAT 2010
Brick red precipitates are formed when aldehydes react with:
-
57UHS MDCAT 2010
Dry distillation of a mixture of calcium salts of formic acid and acetic acid results into the formation of:
-
58UHS MDCAT 2017
In the reaction below “?” represents which one of the following products:
-
59UHS MDCAT 2017
Which one of the following compounds will give iodoform test on treatment with aqueous iodine?
-
60UHS MDCAT 2017
The reactions of aldehydes and ketones with ammonia derivative G-NH3 to form compounds containing >C=N-C and water is known as _ reaction.
-
61UHS MDCAT 2017 (Reconduct)
Both aldehyde and ketones give _:
-
62UHS MDCAT 2017 (Reconduct)
Which reagent is responsible for the conversion of ketone to secondary alcohol:
-
63UHS MDCAT 2019
Which of the following will give a positive test with Tollen’s reagent?
-
64UHS MDCAT 2019
Identification tests for functional groups of organic compounds are associated with specific observations. Tollen’s reagent is an ammoniacal silver nitrate solution, which is used for the identification of a functional group X with an observation O. Identify X and O.
-
65UHS MDCAT 2023
What is the IUPAC name of di-isopropyl ketone?
-
66UHS MDCAT 2024 NUMS MDCAT 2023
CnH2nO is the general formula of:
-
67PMDC MDCAT 2025
Acetaldehyde undergoes oxidation to produce acetic acid, In this reaction oxidizing agent used is
-
68
Which of the following tests are given by both aldehyde and ketones?
-
69
The structure and hybridization of carbonyl carbon in alkanal and alkanone is
-
70
Formalin is
-
71Balochistan MDCAT 2024
Which one of the following statements is NOT correct?
-
72Balochistan MDCAT 2024
The IUPAC name for formaldehyde is:
-
73KPK MDCAT 2024
Which aldehyde is more reactive towards nucleophilic addition:
-
74FMDC MDCAT 2024
The IUPAC name of given organic compound isСН3-CH(Cl)-CH2-CH2-CHO
-
75FMDC MDCAT 2024
The correct reactivity order of the following compounds towards nucleophile is
-
76UHS MDCAT 2024
The blue color of Fehling solution is changed to red when warmed with an aldehyde due to the formation of which of the following?
-
77UHS MDCAT 2024
The reaction of formaldehyde with HCN is:
-
78Sindh MDCAT 2024
Aldehydes & ketones can be converted to alkane. This reaction is called:
-
79Sindh MDCAT 2024
Ketones, when treated with LiAlH4, reduce to:
-
80Balochistan MDCAT 2022
Which of the following compounds will react with Tollens reagent to give metallic silver?
-
81Balochistan MDCAT 2022
The IUPAC name of CH3-O-C2H5 is
-
82NUMS MDCAT 2023 FMDC MDCAT 2022
Catalytic reduction of aldehyde & Ketone forms:
-
83
When aldehyde reacts with 50 % NaOH this reaction is called _.
-
84KPK MDCAT 2022
Acetone reacts with hydrogen cyanide (HCN) to form a cyanohydrin. It is an example of?
-
85UHS MDCAT 2022
Which of the following is incorrect?
-
86UHS MDCAT 2022
Which of the following is the correct name of CH3CH2CH2COCH2CHO?
-
87UHS MDCAT 2022
When Phenol reacts with formaldehyde, which of the following product is produced?
-
88Sindh MDCAT 2022
Addition product of formaldehyde & ethyl alcohol is:
-
89Sindh MDCAT 2022
Acetophenone is an:
-
90Sindh MDCAT 2022
Aldehyde reacts with:
-
91Sindh MDCAT 2022
Nylon 4.6 is:
-
92Sindh MDCAT 2022
Acetone gives:
-
93Balochistan MDCAT 2023
What occurs when carbonyl compounds react with HCN
-
94Balochistan MDCAT 2023
By base-catalyzed reaction
-
95
Silver Mirror with Tollens Reagent is formed by
-
96Sindh MDCAT 2023 (Retake)
Which of the following reactions is NOT shown in ketones?
-
97
Fehling's solution works on the principle of redox reaction which results in:
-
98
Aldehyde and ketone on reaction with hydroxylamine form:
-
99
The reduction of aldehyde and ketone is to alkanes in the presence of Zinc amalgam and HCl is called
-
100UHS MDCAT 2023
The appearance of a silver mirror in Toliens test indicates the presence of which of the following?
-
101
What is the IUPAC name of diisopropyl ketone?
-
102FMDC MDCAT 2023
Aldehydes do not give which identification test:
-
103
Aldehydes cannot be easily oxidized by:
-
104FMDC MDCAT 2023
The function of NaOH in Adol condensation & Cannizaro's reaction respectively is:
-
105Sindh MDCAT 2023
Which of the following produce maleic anhydride on oxidation?
-
106Sindh MDCAT 2023
Oxidation of Toluene by KMnO4, the product is:
-
107Sindh MDCAT 2023
Which of the following is formed when acetone is oxidized?
-
108Sindh MDCAT 2023
Dry distillation of which of the following can be done to produce acetone?
-
109Sindh MDCAT 2023
Which of the following is formed when form aldehyde is treated with oxidizing mixture (H2SO4+K2Cr2O7)
-
110
Why does hydrogen cyanide add to propanone but not to propene?
-
111
Acetaldehyde is purified by which method when prepared by alcohol in laboratory:
-
112
Which of the following is correct statement regarding carbonyl compounds:
-
113
For this reaction, the question mark represents:
-
114
Which of the following pairs can be distinguished by Fehling's solution?
-
115
Mark the incorrect statement about aldehydes and ketones.
-
116
Which of the following does not give aldol condensation reactions?
-
117
Which of the following carbonyl compounds does not shows rapid reaction with sodium nitroprusside
-
118
Formalin is_% solution of formaldehyde in water
-
119
Formation of cyanohydrin from an aldehyde is an example of:
-
120
Ketones react with NaBH₄ to produce:
-
121
Which one is aldehyde:
-
122
In carbonyl compounds carbonyl carbon is bonded to_
-
123
The reagent with which both acetaldehyde & acetone react easily is:
-
124
The flavour of amyl butyrate is:
-
125
Acetone is less reactive than acetaldehyde due to:
-
126
lodoform test is used to check the presence of:
-
127
When two moles of acetone are treated with a base, the product is?
-
128
AcetaIs are:
-
129FMDC MDCAT 2018
Methyl ketones can be characterised by performing:
-
130FMDC MDCAT 2018
Cannizzaro's reaction is NOT given by:
-
131FMDC MDCAT 2018
Cyanohydrins can be synthesised from ketones through:
-
132ETEA MDCAT 2017
The oxidation of pent-2-one with nascent oxygen gives:
-
133UHS MDCAT 2017 (Reconduct)
Identify the compound, which gives positive iodoform test:
-
134UHS MDCAT 2017 (Reconduct)
To distinguish aldehyde from ketone which solution is used:
-
135UHS MDCAT 2017 (Reconduct)
Reaction of alcohol with hydrogen chloride yields:
-
136UHS MDCAT 2016
CH3COOH + PCl5 → ?
-
137UHS MDCAT 2016
Which one of the following tests is given by both aldehydes and ketones?
-
138UHS MDCAT 2016
Which one of the following is the IUPAC name of the structure given below?
-
139UHS MDCAT 2016
Which one of the following is an appropriate indication of positive iodoform test?
-
140UHS MDCAT 2013
Which of the following is the structure of ketone?
-
141UHS MDCAT 2013
What is the structure of alcohol which on oxidation with acidified Na2Cr2O7 gives:
-
142UHS MDCAT 2013
Which group gives a yellow precipitate of triiodomethane when warmed with alkaline aqueous iodine?
-
143UHS MDCAT 2014
For the following reaction, what does the question mark represent?
-
144UHS MDCAT 2014
The structural formula of the product of reaction of acetone with 2,4-dinitrophenyl hydrazine is:
-
145UHS MDCAT 2014
A student mixed ethyl alcohol with a small amount of sodium dichromate and added it to the hot solution of dilute sulphuric acid. A vigorous reaction took place. He distilled the product formed immediately. What was the product?
-
146UHS MDCAT 2014
Which one of the following compounds is a ketone?
-
147
CH3CN +H2O + HCl → A + B In the reaction given above, A and B are:
-
148UHS MDCAT 2011
Which one of the following compounds belongs to the homologous series of aldehydes?
-
149UHS MDCAT 2011
In the below reaction, the nucleophile is:
-
150UHS MDCAT 2011
Consider the following reaction:R―CHO + 2[Ag(NH3)2]OH → R―COONH4 + 2Ag + 2NH3 + H2O. This reaction represents one of the following tests?
-
151UHS MDCAT 2011
An alcohol is converted to an aldehyde with same number of carbon atoms as that of alcohol in the presence of K2Cr2O7/H2SO4 the alcohol is:
-
152UHS MDCAT 2015
Both aldehydes and ketones are planar to the neighborhoods of the carbonyl (C=O) group. Which one of the following bonds is distorted towards the oxygen atoms?
-
153UHS MDCAT 2022 UHS MDCAT 2015
Which one of the following is also called the silver mirror test?
-
154
Ketones can be oxidized by _?
-
155
Which of the following product is formed when aldol is heated?
-
156
If both alkyl groups attached to the carbonyl in ketone are the same, then it is called as:
-
157
In nomenclature, aldehyde group in all aldehydes are given position 1 and its position is not mentioned in the name because?
-
158
Which of the following products are formed from 'Cannizzaro's reaction'?
-
159
Aldol consists of which functional group?
-
160
Aldol condensation takes place in the presence of _ ?
-
161
Both ketones and aldehydes are present in _ ?
-
162
During oxidation of unsymmetrical ketones which atom is oxidized?
-
163
40% aqueous solution of formaldehyde is called:
-
164PMC Practice Test 2 2021 PMC Practice Test 5 2021
Condensation involves which of the following reactions?
-
165
Reduction of ketones produces:
-
166
Which of the following product is formed when alcohol is added to acetaldehyde?
-
167
In aldol condensation, nucleophile is _.
-
168
Which of the following test can detect presence of both aldehydes and ketones?
-
169
Which one is the correct geometry of acetal?
-
170
During benedict's solution test brick red precipitates are formed due to formation of _ ?
-
171
Aldehydes are obtained by the oxidation of which of the following?
-
172
Which one of the following is formula of iodoform?
-
173
Aldehydes can be oxidized by _.
-
174
Formalin is an aqueous solution of:
-
175
Which of the following compound is not reduced by NaBH4 ?
-
176PMC Practice Test 1 2021 PMC Practice Test 1 2022
The carbonyl compound which is attached with at least one H atom at one side is called as?
-
177
By the oxidation of symmetrical ketone, which of the following products are formed?
-
178
In IUPAC nomenclature, ketones are named as _.
-
179
The Addition of Hydrogen cyanide to Formaldehydes gives which product?
-
180
Bulky ketones do not react with
-
181
For aldol condensation, carbonyl system must have _.
-
182
Which of the following reaction of carbonyl system is used to distinguish between carbonyl system from alcohols?
-
183
The reaction of two similar carbonyl compounds to give aldol product is called as _?
-
184
In the addition of sodium bisulfite to carbonyl system, which of the following is nucleophile?
-
185
During base catalyzed reactions, which property of "nucleophile" increases?
-
186
Which of the following undergoes Cannizzaro reaction ?
-
187
Both "Ketones" and "Aldehydes" are present in _.
-
188
Self-oxidation reduction reaction is also called as _?
-
189
Base catalyzed reaction of carbonyl group takes place in the presence of:
-
190
Formaldehyde is used in vat dyeing as?
-
191
Which of the following is used in the silvering of mirrors in industries?
-
192
In the normal nomenclature, the aldehyde group in all aldehydes is given position 1 and its position is not mentioned in the name because _.
-
193
What is the hybridization of the carbon atom in an Aldehyde group?
-
194
In acid-catalyzed nucleophilic addition reactions, which of the following property does the carbonyl system enhance?
-
195
Bisulphate addition product when heated with mineral acid yield?
-
196
Aldehyde reacts with Ammonia to form all of the following except:
-
197
Which of the following is the function of formalin?
-
198
In which of the following reagents, cupric citrate complex is formed?
-
199
Formaldehyde polymerizes to form?
-
200
On an industrial scale, which catalyst is used for the preparation of methanal?
-
201
Aldehydes and ketones are _ ?
-
202
Why is the oxidation of ketones not easy?
-
203
Addition of ammonia and its derivative catalyze by _?
-
204
Acetaldehyde oxidation will lead to formation of _.
-
205
Aldol condensation takes place in the presence of _.
-
206
In ketones, the carbonyl carbon is directly attached to:
-
207
Ketones undergo reduction to form:
-
208
Acetylene reacts with HgSO₄ and H₂SO₄ to form:
-
209
Acetaldehyde reacts with a Grignard reagent (CH₃MgBr)followed by hydrolysis to form:
-
210
Identify the common name of the following compound:CH₃CH₂COCH₂OH
-
211
The FORMYL functional group is:
-
212
Formaldehyde and Grignard's reagent produces:
-
213
Formamint's composition is:
-
214
Meta-formaldehyde is formed by:
-
215
During preparation of Acetaldehyde from ethanol in laboratory, why acetaldehyde is distilled off quickly after formation?
-
216
Reaction of Aldehydes with the Tollen's reagent results in the formation of _?
-
217PMC Practice Test 4 2021
Distillation of calcium acetate and calcium formate produces?
-
218PMC Practice Test 4 2021
From which of the following ketone can be prepared?
-
219
Acetaldehyde in the presence of Conc.H2SO4 undergoes _ ?
-
220UHS MDCAT 2018
Which mechanism of reactions is shown by carbonyl compounds?
-
221UHS MDCAT 2018
Which compound will be produced by the oxidation of ethanal by acidified K2Cr2O7 ?
-
222
Acetaldehyde undergoes polymerization with concentrated H2SO4 to form _.
-
223PMC Practice Test 2 2021
Which of the following compounds give a positive silver mirror test?
-
224
Which of the following will give a positive test with Tollen's reagent?
-
225
Identification tests for functional groups of organic compounds are associated with specific observations. Tollen's reagent is an ammoniacal silver nitrate solution, which is used for the identification of a functional group X with an observation O. Identify X and O.
-
226UHS MDCAT 2019
Select the reagent X from the following choices for this conversion:
-
227
Which of the following is the correct IUPAC name of acetone?
-
228PMC Practice Test 4 2021
What is the nature of Carbon present in Aldehyde is?
-
229
Which of the following compound is present in camphor and menthone?
-
230
Cyanohydrins, when reacted with mineral acid, produce _.
-
231PMC Practice Test 3 2021
Which of the following centers are present in the carbonyl compounds?
-
232
The electrophile in aromatic sulfonation is:
-
233
Which class of the compounds is represented by the type formula ROR?
-
234
Methyl ketones can be characterized by performing:
-
235
Cyanohydrins can be synthesized from ketones through:
-
236NUMS MDCAT 2019
Which of the following can be oxidized to an aldehyde?
-
237
What is the color of the precipitate when Brady's reagent is used to test a benzaldehyde?
-
238
A diabetic person's exhaled breath contains propanone. A student tries to test the diabetes by asking the person to bubble the reagent with his exhaled breath. Which of the following reagents would give a positive result?
-
239
Carbonyl group undergoes:
-
240
Hybridization of carbon in -CHO group is:
-
241NUMS MDCAT 2020
2-Butanone on oxidation with K2Cr2O7 / H2SO4 forms:
-
242Sindh MCAT NTS 2016 SMBBMC Lyari
The following reaction is an example of:
-
243
Ketone reacts with Grignard reagent to form _ in acidic media?
-
244PMDC MDCAT 2020
Which of the following reagent is used to separate and purify carbonyl and non carbonyl compounds?
-
245PMDC MDCAT 2020
The common name of the following aldehyde is:
-
246Sindh MCAT NTS 2018
Which of the following reactions is NOT shown by ketones?
-
247Sindh MCAT NTS 2011 DUHS and JSMU
ROR is the general formula of:
-
248
Which of the following will react with water?
-
249
Treatment of propionaldehyde with Dil. the NaOH solution gives:
-
250Sindh MCAT NTS 2010 DUHS and JSMU Sindh MCAT NTS 2009
The general formula for an aldehyde is:
-
251
Tincture of Iodine is:
-
252UHS MDCAT 2019
Which type of reaction takes place when a carbonyl compound is treated with a mixture of NaCN and an acid?
-
253
The common name for 2-propanone is:
-
254
Which of the following reaction takes place when acetone reacts with HCN ?
-
255NUMS MDCAT 2019
What type of chemical reaction is this?CH3CHO + NH3 -> CH3CH(OH)NH2
-
256
Which of the following does not give iodoform test?
-
257
Phenylmethyl ketone can be converted into ethyl benzene in one step by using:
-
258UHS MDCAT 2019
Ketones can be made by oxidation of:
-
259UHS MDCAT 2018
Which one of the following reagents is used to distinguish between aldehydes and ketones?
-
260
Which of the following will not undergo aldol condensation?
-
261
In Cannizzaro's reaction, Benzyl alcohol is obtained from?
-
262UHS MDCAT 2018
Why is it necessary to distill aldehyde formed from oxidation of primary alcohol through acidified potassium dichromate (VI) solution or acidified sodium dichromate (VI) solution?
-
263
Which of the following is more soluble in water?
-
264ETEA MDCAT 2019
Which one is more reactive?
-
265
Most common reaction showed by alkyl halide is:
-
266
Nucleophilic addition reactions of carbonyl compounds can be catalyzed by_?