Chemistry of Hydrocarbons

MDCAT • Chemistry

500 MCQs — Click "Reveal" to see the correct answer

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  1. 1
    NUMS MDCAT 2024
    The most readily sulphonated compound is:
  2. 2
    Identify the alkene which gives only one type of aldehyde upon ozonolysis:
  3. 3
    Balochistan MDCAT 2024
    When a hydrogen atom of an alkane is removed, the resulting group is called:
  4. 4
    Benzene when reacts with chlorine in presence of sunlight gives additional product, i.e.:
  5. 5
    In alkane series, all the linkages between carbon atoms are which type of bonds?
  6. 6
    Which is regarded as the simplest and the parent member of aromatic class of compounds?
  7. 7
    Balochistan MDCAT 2024
    Natural gas consists mainly of:
  8. 8
    Sindh MDCAT 2024
    The density of benzene is:
  9. 9
    When chlorobenzene reacts with sodium hydroxide at 350°C and 150 atmospheric pressure, it gives formation of:
  10. 10
    Sindh MDCAT 2024
    The bond length between C-C in benzene is:
  11. 11
    When an unsymmetrical alkene undergoes addition reactions, the negative part of the attacking reagent is added to that double-bonded carbon atom which contains:
  12. 12
    The carbon atom carrying positive charge and attached to three other atoms or groups is called:
  13. 13
    Addition of HBr to isobutylene mainly gives:
  14. 14
    The homolytic fission of C-H bond in an alkane results in:
  15. 15
    FMDC MDCAT 2024 (Reconduct)
    Resonance energy of benzene is:
  16. 16
    FMDC MDCAT 2024 (Reconduct)
    The common name of 1,3-dihydroxy benzene is:
  17. 17

    What is the IUPAC name of given compound? CH3-CH=CH-CH2-C≡CH

  18. 18
    FMDC MDCAT 2024
    Which type of catalyst is used during electrophilic substitution reactions of benzene?
  19. 19
    FMDC MDCAT 2024
    Which compound is used as a reference for calculating the extent of stability of benzene?
  20. 20

    The saturated alicyclic hydrocarbons have the general formula:

  21. 21
    What will be the IUPAC name of neopentane?
  22. 22

    In Friedel Craft acylation, an acyl group is introduced in benzene ring in the presence of catalyst:

  23. 23

    Which of the following is an example of a substituent group which releases electrons to the benzene ring?

  24. 24
    Balochistan MDCAT 2023
    The hydrocarbon which has isolated rings and is aromatic?
  25. 25
    What do we mean by the term 'delocalized electrons' in benzene?
  26. 26
    The acylium ion has a positive charge and acts as?
  27. 27
    What of the following produces maleic anhydride on oxidation?
  28. 28
    Oxidation of toluene by KMnO4 gives the product:
  29. 29
    Benzene is subjected to (1) Alkylation (2) Nitration (3) Oxidation. The product is:
  30. 30

    When benzene reacts with isopropyl chloride in the presence of AlCl3 as Lewis acid (Friedel Craft Acylation), the product formed is isopropyl benzene. What is this reaction called?

  31. 31

    What hybridization is present on carbon atoms in Ethyne C2H2?

  32. 32

    Among the following hydrocarbons, which one has acidic hydrogen?

  33. 33

    Identify the electrophile called as acylium ion:

  34. 34

    Which one of the following is not a meta directing group?

  35. 35
    FMDC MDCAT 2023
    Which compound is least reactive?
  36. 36
    If both double and triple bonds are present, then the ending given to the root is:
  37. 37
    FMDC MDCAT 2023

    Which of the following will not give substitution reaction?

  38. 38
    Under suitable conditions, alkanes cannot undergo which reactions?
  39. 39
    The resonance energy of benzene is how many KJ/mole more stable than expected?
  40. 40
    Which isomer of pentane has least melting and boiling point?
  41. 41

    IUPAC name of the following compound CH3-(CH3)2-C(CH3)3 is:

  42. 42
    Balochistan MDCAT 2022
    Michael Faraday discovered benzene in the gas formed from?
  43. 43

    Benzene also undergoes electrophilic substitution when treated with fuming sulphuric acid for several hours. The electrophile in this reaction is?

  44. 44
    Benzene is subjected to alkylation, nitration & oxidation. The product is:
  45. 45
    Isopropyl benzene is also called:
  46. 46

    The electrophile which is considered to be the active agent in the nitration of benzene is:

  47. 47

    Propyne reacts with aqueous sulphuric acid in the presence of HgSO4 to form:

  48. 48
    Which of the following compounds has highest boiling point?
  49. 49
    Reactivity order of halogen acid is:
  50. 50
    FMDC MDCAT 2023
    The correct order of reactivity of hydrocarbons is:
  51. 51

    Consider the chlorination of CH4, the attack of chlorine free radical on CH4 to form methyl free radical occurs in?

  52. 52

    Alkyl benzene is formed when benzene is treated with an alkyl halide in the presence of anhydrous AlCl3. Identify the type of reaction.

  53. 53

    Which of the following acts as electrophile during nitration of benzene?

  54. 54
    Which of the following is marsh gas?
  55. 55
    Benzene does not show:
  56. 56
    Ethene has how many pi bonds?
  57. 57

    When CH3 is attached with the benzene ring, it makes the ring:

  58. 58
    Acetophenone can be formed by which of the following reaction of benzene?
  59. 59
    PMDC MDCAT 2020

    Electrophile in sulphonation of benzene is:

  60. 60
    Treatment of ethene with cold sulphuric acid followed by reaction with boiling water yields:
  61. 61

    An olefin 'X' on ozonolysis gives CH3CH2COCH3 and CH3COCH3. The IUPAC name of X is:

  62. 62

    A gas decolorizes alkaline KMnO4 solution but does not give any PPT with ammonical AgNO3:

  63. 63

    Select meta directing group of the following:

  64. 64

    The correct order of the reactivity of hydrocarbon given below is:

  65. 65
    Which of the following compounds reacts slower than benzene in electrophilic substitution reaction?
  66. 66

    Which catalyst is used in oxidation of benzene ring?

  67. 67
    Acetone can be obtained by ozonolysis of:
  68. 68

    Order of reactivity of halogen toward alkane is:

  69. 69
    Homolysis of a covalent bond yields a very reactive species with incomplete octet in its valence shell. What is this species?
  70. 70

    In the reaction sequence: H3C-CH2 + Br2 → A, then A + alc.KOH → B. The end product is an unsaturated hydrocarbon. Identify the nature of reaction in the two steps.

  71. 71

    Which of the options show all possible products of combustion of Butene?

  72. 72

    In Friedel-Craft's Chlorination of Benzene, Iron III chloride acts as a catalyst. Which is the initial reaction in the generation of an electrophile?

  73. 73

    Which one of the following acts as an electrophile in the electrophilic substitution of benzene with bromine?

  74. 74

    Bromination of alkene is shown in the following reaction. The reaction is used for:


    MCQ image
  75. 75
    Reaction mechanism of alkanes with halogens is known as:
  76. 76

    Among the following, which one has electron withdrawing effect?

  77. 77

    For halogenation of benzene, which reagent is used?

  78. 78

    Which of the following species are 3,5 (meta) directing groups when a second group is introduced into the benzene ring? I = -NH2,

    II = -CHO,

    III = -COOH,

    IV = CH3

  79. 79

    The mechanism of reaction of benzene with bromine in the presence of FeBr3 follows the:

  80. 80

    Which one of the following is a powerful electrophile used to attack on the pi electrons of benzene ring?

  81. 81
    The introduction of R-C=O group in benzene is called:
  82. 82
    Ethene on polymerization gives the product polyethene. This reaction may be called as:
  83. 83

    Benzene in presence of AlCl3 gives acetophenone when reacts with:

  84. 84

    The substitution of -H group by -NO2 group in benzene is called:

  85. 85

    Ethyne molecule is formed when two carbon atoms joined together to form a sigma bond only by:

  86. 86

    The introduction of NO2 group in the benzene ring is called nitration. The nitration of benzene takes place when it is heated with a 1:1 mixture at 50-55°C of:

  87. 87
    When hydrogen atom is removed from benzene, the group left is called:
  88. 88
    UHS MDCAT 2008

    In this process, higher hydrocarbons can be cracked at lower temperature and lower pressure:

  89. 89
    UHS MDCAT 2008

    In which of the following is carbon double bonded with itself?

  90. 90
    UHS MDCAT 2008

    Alkanes containing _ carbon atoms are waxy solids.

  91. 91
    UHS MDCAT 2009

    Which compound is the most reactive one?

  92. 92
    UHS MDCAT 2009

    During nitration of benzene, the active nitrating agent is:

  93. 93
    UHS MDCAT 2010

    The introduction of NO2 group in benzene ring is called ‘Nitration’. The nitration of benzene takes place when it is heated with a 1:1 mixture of _ at 50-55.

  94. 94
    UHS MDCAT 2010

    Symmetrical alkanes can be produced by:

  95. 95
    UHS MDCAT 2010

    Ethyne molecule is formed when two carbon atoms joined together to form a sigma bond by:

  96. 96
    UHS MDCAT 2010

    A gasoline of higher octane number can be obtained by:

  97. 97
    UHS MDCAT 2011

    The substitution of a '-H' by '-NO2' group in benzene is called:

  98. 98
    UHS MDCAT 2011

    Benzene in the presence of AlCl3 produces acetophenone when reacts with:

  99. 99
    UHS MDCAT 2011

    Hydrogenation of unsaturated oils is done by using:

  100. 100
    UHS MDCAT 2012

    The introduction of the following group in benzene is called:

    O

    ||

    R - C -

  101. 101
    UHS MDCAT 2015

    The IUPAC name of the given compound is:


    MCQ image
  102. 102
    UHS MDCAT 2015

    Which one of the following is a powerful electrophile used to attack on the electrons of a benzene ring?

  103. 103
    UHS MDCAT 2016

    It is the general formula of:


    MCQ image
  104. 104
    UHS MDCAT 2016

    Which one of the following is an appropriate structure for the product of bromination?

  105. 105
    UHS MDCAT 2016

    Skeletal formula of a hydrocarbon is given below. What is the IUPAC name of the compound?


    MCQ image
  106. 106
    UHS MDCAT 2016

    Which one of the following reactions shows the combustion of a saturated hydrocarbon?

  107. 107
    UHS MDCAT 2017

    What will be the product of the reaction given below?

    CH3

    \

    C = O + HCN (in presence of NaCN /HCl) Y?

    /

    C2H5

  108. 108
    UHS MDCAT 2017

    The reaction of bromine with benzene in the presence of FeBr3 follows the mechanism of:

  109. 109
    UHS MDCAT 2017

    When benzene reacts with acetyl chloride (CH3COCl) in the presence of AlCl3, acetophenone is formed. The electrophile in this reaction will be:

  110. 110
    UHS MDCAT 2017

    Which of the following are 3,5 (meta) directing groups when second group is induced in them:i) -NH3

    ii) -CHO iii) -COOH iv) -CH3

  111. 111
    UHS MDCAT 2017

    Immediate product formed when propanoyl chloride reacts with benzene is:

  112. 112
    UHS MDCAT 2017

    Which one of the following is used as a typical catalyst for catalytic cracking?

  113. 113
    UHS MDCAT 2017 (Reconduct)

    How many pi bond(s) are there in ethene?

  114. 114
    UHS MDCAT 2017 (Reconduct)

    Chlorination and Bromination mostly uses:

  115. 115
    UHS MDCAT 2017 (Reconduct)

    What should be the temperature and pressure respectively for catalytic cracking:

  116. 116
    UHS MDCAT 2018

    Bromination of alkene is shown in the following reaction. This reaction is used for:


    MCQ image
  117. 117
    UHS MDCAT 2018

    Which of the following acts as an electrophile in the electrophilic substitution of benzene with bromine?

  118. 118
    UHS MDCAT 2018

    Butane molecules can have a maximum number of isomers.

  119. 119
    UHS MDCAT 2018

    The species which are produced by heterolytic bond breaking and can act as electron pair donors are known as:

  120. 120
    UHS MDCAT 2019

    The names of functional groups in the following compound X are:


    MCQ image
  121. 121
    UHS MDCAT 2019

    Which derivative of benzene shows maximum reactivity in electrophilic substitution reactions?

  122. 122
    UHS MDCAT 2019

    Alkenes undergo:

  123. 123
    UHS MDCAT 2019

    Which of the following molecule shows cis-trans isomers?

  124. 124
    UHS MDCAT 2022

    The ratio of sigma to pi electrons in benzene is?

  125. 125
    UHS MDCAT 2022

    Consider the chlorination of methane, the attack of chlorine free radical on methane form methyl free radical occurs in?

  126. 126
    UHS MDCAT 2022

    Which of the following compound is more acidic?

  127. 127
    UHS MDCAT 2022

    Three alternate single and double bonds in benzene are called?

  128. 128
    UHS MDCAT 2022

    Alkylbenzene is formed when benzene is treated with an alkyl halide In the presence of anhydrous aluminum chloride, Identify the type of reaction.

  129. 129
    UHS MDCAT 2022

    What is the number of isomers of a hydrocarbon having a molecular formula, C4H8?

  130. 130
    UHS MDCAT 2023

    Identify which method is used to prepare Alkynes?

  131. 131
    UHS MDCAT 2023

    Propanone can be prepared from propyne by:

  132. 132
    UHS MDCAT 2023

    When 2-bromopropane reacts with Sodium ethoxide, the major product is/are?

  133. 133
    UHS MDCAT 2023

    Alkylbenzene is formed when benzene is treated with an alkyl halide in the presence of anhydrous aluminum chloride. Identify the type of reaction.

  134. 134
    UHS MDCAT 2023

    Under suitable conditions alkanes cannot undergo _ reactions?

  135. 135
    UHS MDCAT 2023

    The addition reaction of 2-butene with HBr produces?

  136. 136
    UHS MDCAT 2023

    Which of the following reagents can be used to distinguish between 1-Pentyne and 2-Pentyne?

  137. 137
    UHS MDCAT 2024

    Which one of the following represents nitration of benzene correctly?

  138. 138
    UHS MDCAT 2024

    In Friedel Craft acylation an acyl group is introduced in benzene ring in the presence of catalyst:

  139. 139
    UHS MDCAT 2024

    Which of the following is an example of substituent group which release electrons to benzene ring:

  140. 140
    PMDC MDCAT 2025

    In propene pi-bond is formed by sideway overlap of:

  141. 141
    PMDC MDCAT 2025

    Chlorination of benzene in the presence of iron (III) chloride involves mechanism of:

  142. 142
    PMDC MDCAT 2025

    Which one of the following is not a characteristic of benzene?

  143. 143
    PMDC MDCAT 2025

    What is general requirement for free radical substitution reaction of ethane and halogen?

  144. 144
    PMDC MDCAT 2025

    Terminal alkynes show acidic character due to:

  145. 145

    Benzene — (Cl2 / FeCl3) → Y

    — (HNO3 + H2SO4) → Z

    Z in this reaction is possibly:

  146. 146
    The oxidation of toluene by acidified KMnO₄ produces
  147. 147
    Benzoic acid is the main product when ______ is oxidized by acidified K₂Cr₂O₇
  148. 148
    Benzoic acid is the only oxidation product along with formation of H₂O and CO₂ of an organic compound A, when A is treated with acidified potassium dichromate, A is
  149. 149
    X is required when alkyl benzenes are readily oxidized to benzoic acid. X is
  150. 150

    This reaction is an example of:

    MCQ image
  151. 151
    The conversion of benzene into cyclohexane is
  152. 152
    Which of the following is produced by the action of CH₃Cl on benzene in presence of AlCl₃ followed by oxidation in the presence of acidified KMnO₄?
  153. 153
    What is required other than anhydrous AlCl₃, when toluene is prepared by Friedel-Crafts reaction?
  154. 154
    How many π electrons are there in benzene to form delocalized electronic cloud:
  155. 155
    Acetylene gives precipitates with AgNO₃ in ammonium hydroxide solution
  156. 156
    The only alkyne which gives an aldehyde upon addition of water
  157. 157
    In addition of HCl to CH₃CH=CH₂, which one will be added first:
  158. 158
    In which addition reaction Markownikov's rule is not obeyed:
  159. 159
    The test for unsaturation of organic compounds is carried out by treating alkenes with dilute alkaline KMnO₄ solution. The colour of KMnO₄ is discharged with the formation of
  160. 160
    Dehydration of alcohols with conc. H₂SO₄ at 180°C gives:
  161. 161
    The ease of dehydration of alcohols to produce alkenes is of the order:
  162. 162
    The most probable products are when Cl₂ is supplied in very high excess to react with CH₄:
  163. 163

    The 2nd step in chlorination of methane in presence of diffused sun light is

  164. 164
    Oxidation of benzene is possible by
  165. 165
    Sigma bonds in alkanes are
  166. 166
    Which of the following is true for halogenation of CH₄?
  167. 167
    Cis-alkene is obtained from alkynes by
  168. 168
    Which of the following is true for hydrogenation reaction?
  169. 169

    General formula of alkyl group is

  170. 170
    The addition of unsymmetrical reagent to an unsymmetrical alkene takes place in accordance with
  171. 171
    Position of double bond in alkenes can be determined by
  172. 172
    Which of the following compounds is more acidic?
  173. 173
    The number of sigma and pi bonds in 2-butene are
  174. 174
    UHS MDCAT 2019

    Which of the following reactions is used for the production of alcohols on industrial scale?

  175. 175
    UHS MDCAT 2018

    Which compound is obtained by the elimination of bromopropane?

  176. 176

    An activating substituents group activate

  177. 177

    Which of the following is Ortho para directing group

  178. 178

    The compound that can be most readily sulphonated is

  179. 179

    Which of the following substitution of benzene is Ortho para in electrophilic substitution and Ortho para in nucleophilic substitution

  180. 180

    Choose the substituent that will direct meta addition on a benzene ring.

  181. 181

    Which of the following substituents is electron-withdrawing when added to a benzene ring?

  182. 182

    A deactivated substituents groups directs

  183. 183

    The ortho and para-hydrogens possesses:

  184. 184

    The ortho/para directing group among the following is

  185. 185

    Which of the following is the strongest ortho, para directing group :

  186. 186

    Which catalyst is used in Friedel-craft alkylation reaction

  187. 187

    Which of the following aromatic compounds undergo Friedel-Crafts alkylation with methyl chloride and aluminum chloride?

  188. 188

    What is the electrophile in the acylation of benzene

  189. 189

    Which of the following is the most activating in electrophilic aromatic substitution?

  190. 190

    What is the electrophile in the electrophilic substitution reaction of benzene using oleum and conc. H2SO4

  191. 191

    This can be a halide in the Friedel Crafts reaction

  192. 192

    Which of the following will not easily undergo Friedel Crafts reaction?

  193. 193

    In Friedel Craft, Alkylation AICI3 is used to generate

  194. 194

    Reacting bromine with benzene in the presence of sunlight will result in

  195. 195

    Acetophenone is a

  196. 196

    Benzene does not undergo

  197. 197

    During sulphonation of benzene, H2SO4 generates the electrophile

  198. 198

    Benzene is heated in air with V2O5 at 450C it undergoes

  199. 199

    The preparation of benzene from acetylene can also be said as

  200. 200

    What is required other than anhydrous AICI3 when toluene is prepared by Friedal craft reaction

  201. 201

    Replacement of hydrogen of benzene by alkyl group in the presence of alkyl halide & aluminium chloride is known as

  202. 202

    Which of the following groups are most likely to be o, p directing

  203. 203

    In Chlorination of benzene, which of the following acts as an electrophile?

  204. 204

    Nitration of benzene is carried out by which of the following reactive species?

  205. 205

    The hydrolysis of Benzenetrizonide will yield three moles of

  206. 206

    Chemical formula of Benzene is

  207. 207

    There are --- resonance structures available in Benzene.

  208. 208

    With the help of Cyclic polymerization, Benzene can be prepared from

  209. 209

    Physical state of benzene is

  210. 210

    Benzene melts at how many degree Celsius

  211. 211

    Benzene is soluble in

  212. 212

    Which of the following is not a physical property of the Benzene?

  213. 213

    Which is not a physical property?

  214. 214

    Aniline is a derivative of benzene which contains

  215. 215

    How many electrons are there in benzene to form delocalized electronic cloud

  216. 216

    What is the molecular formula of Benzenetriozonide

  217. 217

    Phenanthrene is a fused polycyclic compound contains _ benzene rings

  218. 218

    Ozonolysis of benzene produces

  219. 219

    p-bonds in benzene spread over all six carbons, hence they are called

  220. 220

    The molecular formula of toluene is

  221. 221

    Vanillin is used to give flavor in

  222. 222

    Chlorobenzene is one of the

  223. 223

    In most of the organic compounds, the group found is

  224. 224

    Which is fused cyclic aromatic compound

  225. 225

    Chlorination of toluene in the presence of sunlight produces

  226. 226

    The oxidation reaction of alkyne (ethyne) with alcoholic potassium permanganate produce

  227. 227

    The major alkyne, acetylene compound is produced by which among the following application on natural gas

  228. 228

    When ethyne is passed through a red hot tube, _ is formed

  229. 229

    The transformation into carboxylic acids of the alkynes takes place with the help of which among the following reagents

  230. 230

    Alkynes cannot be prepared from

  231. 231

    Ethyne and Ethane can be separated from a mixture by passing it through

  232. 232

    1-butyne and 2-butyne can be identified by using which of the following reagents

  233. 233

    Which among the following alkynes is used as a rocket fuel

  234. 234

    Which among the following product is formed when ethyne undergoes reaction with HgSO4 and H2SO4

  235. 235

    Acetylene is oxidised by KMnO4 to form

  236. 236

    The product formed in the reaction of ethyne with dilute H2SO4 and Hg2+ is

  237. 237

    Polymerisation product of propyne is

  238. 238

    The product formed in the reaction of propyne with dilute H2SO4 and HgSO4 is

  239. 239

    Water can be added across a triple bond in the presence of

  240. 240

    When propyne is treated with dilute H2SO4 in presence of HgSO4 the major product will be:

  241. 241

    Acetylene is obtained by the electrolysis of

  242. 242

    When ethyne is subjected to ozonolysis of, what is the end product

  243. 243

    Ethyne on oxidation with alcoholic KMnO4 forms _

  244. 244

    Which of the following is used for welding?

  245. 245

    Alkyne are slightly in nature

  246. 246

    Alkynes have a _ bonding strength

  247. 247

    Alkynes have a _ boiling point than alkanes

  248. 248

    Alkynes are slightly _ in nature.

  249. 249

    The boiling and melting points of alkynes -------- as their molecular structure becomes more complex.

  250. 250

    The first three alkynes have state of matter

  251. 251

    Unsaturated carbon with how many bonds at the carbon site is known as alkynes.

  252. 252

    The 'sp' hybridization is present in:

  253. 253

    Write the IUPAC name of the following alkyne compound

  254. 254

    Are alkynes more reactive than alkenes

  255. 255

    What is a general formula of alkynes

  256. 256

    Acetylene contains:

  257. 257

    Different members of alkynes are named in the form of _ derivatives

  258. 258

    The nomenclature of alkynes is quite similar to the nomenclature of _

  259. 259

    Terminal alkynes and internal alkynes are the _forms of alkynes.

  260. 260

    Tetrahydroxy ethane loses two water molecules to form

  261. 261

    Glyoxal formed by loss of two water molecules by tetrahydroxy ethane oxidizes to

  262. 262

    Alkynes show _ reactions

  263. 263

    The first member of the alkyne homologous series' is

  264. 264

    Alkanes, alkenes and alkynes is the combination of which of the following elements:

  265. 265

    Oxy-acetylene torches can produce temperature as high as

  266. 266

    What type of reaction do alkynes undergo across the triple bond

  267. 267

    Which of the following are saturated hydrocarbons?

  268. 268

    Acetylene is also called

  269. 269

    Which of the following compounds react most readily with Br(g)

  270. 270

    Which of following is not colorless

  271. 271

    Which of the following statement is true regarding the reactivity order in order to form alkyl halides

  272. 272

    Addition reaction of hydrogen Bromide to the unsymmetrical alkene follows _

  273. 273

    In Alkenes the Carbon atoms are connected to each other by a

  274. 274

    What causes the red color of tomatoes?

  275. 275

    Addition of hydrogen to ethene forms

  276. 276

    When bromine water is added to an alkene, the product is

  277. 277

    When two carbon atoms share three electron pairs then they form

  278. 278

    The catalyst which is used to break hydrocarbons is

  279. 279

    The lower molar mass of hydrocarbons has increased

  280. 280

    Alkenes mostly follow the reaction of

  281. 281

    If ethene is a reactant, then the product will be

  282. 282

    Under certain conditions, the ethene molecule reacts to give

  283. 283

    The double bond in ethene is formed from a

  284. 284

    Addition reaction of hydrogen Bromide to the unsymmetrical alkene follows _ Alkenes can be oxidized by the help of a powerful oxidizing agent, acidified

  285. 285

    Alkenes show _ isomerism Unsaturated oils become partially saturated when they are reacted with

  286. 286

    Hydrocarbons containing double bonds are called

  287. 287

    C=C has a high electron density area hence it is

  288. 288

    Alkenes (C=C) are known to be _ hydrocarbon

  289. 289

    C5-C15 members of alkenes are

  290. 290

    How much ethene is required for the ripening of 1 kg of tomatoes

  291. 291

    Which of the following processes involves the addition of hydrogen molecule across carbon-carbon multiple-bond?

  292. 292

    Higher members of alkenes are

  293. 293

    Due to the presence of double bonds, alkenes are

  294. 294

    Ethene is prepared from chloroethane this is an example of a reaction _

  295. 295

    At which temperature and pressure ethene is polymerized to polyethylene and polyurethane?

  296. 296

    In this process small organic molecules (monomer) combine together to form Larger molecules known as

  297. 297

    The reduction of ozonides produces

  298. 298

    Ozone O3 is highly reactive allotropic form of

  299. 299

    The presence of unsaturation is also detected by

  300. 300

    The Baeyer's reagent act as

  301. 301

    The Baeyer's reagent has colour of?

  302. 302

    Most alkenes are hydrogenated over Raney nickel at about

  303. 303

    Raney nickel is a spongy form of _ . It has porous surface

  304. 304

    Catalytic hydrogenation of alkenes is used in industry for the manufacturing of

  305. 305

    The heat of hydrogenation of most alkene is about - for each double bond present in a molecule

  306. 306

    Baeyer's reagent is

  307. 307

    The presence of double and triple bond in a compound is the sign of

  308. 308

    Alkenes show weakly polar property because of

  309. 309

    Alkenes are soluble in

  310. 310

    C5 to C15 are........

  311. 311

    Which members of alkene are Gases at room temperature

  312. 312

    CH2=CH-CH=CH2 the name of this compound

  313. 313

    In alkene the numbering begins from the end nearest to the

  314. 314

    Designate the location of double bond by using the number of the.....of the double bond as a prefix

  315. 315

    Longest continuous chain of alkene containing parents chain of

  316. 316

    The alkene are given name by alkanes by changing the identical 'ane' to

  317. 317

    Alkene containing two double bond are known as

  318. 318

    The general formula for alkene

  319. 319

    The simplest olefins is

  320. 320

    Alkenes are also known as

  321. 321

    Alkene has ...... hydrogen atom less than the corresponding saturated hydrocarbons

  322. 322

    N2H4//KOH is used as...... in wolf kishner reduction

  323. 323

    The general formula having by alkanes is

  324. 324

    In alkane the carbon is bonded by

  325. 325

    Unsaturated hydrocarbons are known asAlkanes

  326. 326

    Saturated hydrocarbons are also known as

  327. 327

    When methane reacts with Cl2 in the presence of diffused light, the product obtained are:

  328. 328

    Beta and beta prime dicholoro ethyl sulphide is commonly known as

  329. 329

    Preparation of vegetable ghee involves

  330. 330

    In Clemmensen reduction Zn-Hg/HCl and in in Wolf kishner reduction N2H4/KOH is used to generate

  331. 331

    Alkyl halides react in anhydrous ether with magnesium to form alkyl magnesium halides known as

  332. 332

    Wolf kishner 's readuction reduces aldehyde into

  333. 333

    Clemmensen reduction is the reduction of

  334. 334

    Kolbe's electrolytic method takes place in the presence of

  335. 335

    Decarboxylation of monocarboxylic acid reaction of alkanes takes place in the elimination of

  336. 336

    Addition of hydrogen accompanied by a bond cleavage is called

  337. 337

    Which catalyst is used in hydrogenolysis

  338. 338

    Which cleavage takes place in hydrogenolysis

  339. 339

    Which cleavage takes place in hydrogenation

  340. 340

    Sabatier -sendern's reaction can be used to prepare

  341. 341

    The hydrogenation Reactions of alkanes at 200°C-300°C temperature, takes place in the presence of

  342. 342

    The addition of hydrogen in alkenes or alkynes in the presence of nickel at 200-300°C yields alkanes is called

  343. 343

    The alkanes has geometry

  344. 344

    Each carbon atom in alkane has hybridization

  345. 345

    Alkanes are also known as

  346. 346

    Alkanes are simplest organic compounds made up of carbon and…… only

  347. 347

    The formula of dicholoro methane is

  348. 348

    Which type of reaction are given by alkanes

  349. 349

    Alkanes are non -polar they are soluble in

  350. 350

    Find the compound with the highest boiling point among the following

  351. 351

    Paraffin wax is

  352. 352

    If we remove one hydrogen atom from alkane the rest of group is called

  353. 353

    The name marsh gas was given to:

  354. 354

    The self linking property of carbon atom is called

  355. 355

    The reaction of propane with bromine is called?

  356. 356

    An alkane with 7 carbon atoms contains _ hydrogen atoms.

  357. 357

    Find the alkane (C5H12), which will give only one type of monohalogenated compound

  358. 358

    The substituent in the chain is named by replacing the "ane" in the alkanes by _

  359. 359

    Identify the smallest alkane which can form a ring structure (cycloalkane)?

  360. 360

    Identify the correct alkane name for the molecular formula C30H62

  361. 361

    Saturated hydrocarbons are otherwise referred as _

  362. 362

    Which among the following is not an alkane isomer with 6 carbon atoms?

  363. 363

    Select the minimum number of carbon atoms, a molecule must possess so as to be regarded as a higher alkane.

  364. 364

    Identify the simplest alkane

  365. 365

    Select the incorrect statement regarding alkanes.

  366. 366

    When different alkenes are treated with hot concentrated KMnO4 solution, different products are obtained. Which of the following alkenes produces two moles of carboxylic acids?

  367. 367

    Which one of the following is a powerful electrophile used to attack On the electrons of benzene ring?

  368. 368

    Skeletal formula of an organic compound iv given below: It is a hydrocarbon. IUPAC name of the compound is:

  369. 369

    Chlorination and bromination of alkanes can be done mostly in the presence of:

  370. 370

    In β-elimination reaction, _ is used:

  371. 371

    Structural formula of 2,3,4-Trimethylpentane is:

  372. 372
    UHS MDCAT 2017 (Reconduct)

    Catalytic oxidation of alkanes results in the formation of _:

  373. 373
    UHS MDCAT 2017 (Reconduct)

    For halogenation of benzene, which reagent is used:

  374. 374

    Consider the following structure: Which one of the following is an appropriate name of above compound?

  375. 375

    o- and p-nitrophenol are formed by the reaction of _ with phenol at 25°C:

  376. 376

    Phenol undergoes ionization to become more stable by reacting with which of the following chemical species?

  377. 377

    The reaction of benzene with bromine in the presence of FeBr3 follows the mechanism of _ reaction:

  378. 378

    4-Bromobut-1-ene is the name of which among the following alkenes?

  379. 379

    When benzene reacts with acetyl chloride (CH3COCI) in the presence of AlCl3, acetophenone is formed. The electrophile in this reaction will be:

  380. 380

    Which of the following species are 3,5 (meta) directing groups when second group is introduced into the benzene ring: I = -NH2 II = -CHO III = -COOH IV = -CH3

  381. 381
    UHS MDCAT 2015

    The given three hydrocarbons are:

  382. 382
    UHS MDCAT 2015

    Order of reactivity of alkenes with hydrogen halide is:

  383. 383
    UHS MDCAT 2013

    What is the product formed when propene reacts with HBr?

  384. 384
    UHS MDCAT 2014

    Addition of unsymmetrical reagent to an unsymmetrical alkene is governed by:

  385. 385

    Bakelite is formed when phenol react with which of the following reactant?

  386. 386

    In hich of the following carbon is double bonded with itself?

  387. 387

    Butyne and 2-Butyne can be identified by using which of the following reagents?

  388. 388

    Hydrogen passed through phenol at 150°C in the presence of _ catalyst gives cyclohexanol:

  389. 389
    UHS MDCAT 2008

    Ten moles of hydrogen are allowed to react with 6 moles of oxygen. How much water will be obtained from reaction on complete consumption of one gas?

  390. 390

    Alkanes containing _ carbon atoms are waxy solids:

  391. 391

    Alkanes mostly give _?

  392. 392

    The conversion of n-hexane to benzene by heating is called:

  393. 393

    Which of the following statements is/are correct?

  394. 394

    The simplest member of organic compounds is?

  395. 395

    Benzene is extra stable because of _?

  396. 396

    Bomine/water reacts with phenol and decolorize orange colour and turns it to which of the coloured precipitate?

  397. 397

    Ethylene bromide on treatment with Zn gives:

  398. 398

    The reactivity of alkenes is due to the presence of?

  399. 399

    What is the value of C-C bond length in benzene?

  400. 400

    Formation of picric acid by phenols is called

  401. 401

    In sp2 hybridization the orbital orientation is:

  402. 402

    Alkynes show _ reactions.

  403. 403

    Which of following shows maximum boiling point

  404. 404

    Hydrocarbons are organic compounds with element _:

  405. 405

    How carboxylic acid group attached to the benzene ring affect its reactivity?

  406. 406

    Ethyne on oxidation with strong alkaline KMnO4 forms:

  407. 407

    Which one of the following is correct structure of benzene?

  408. 408

    When phenol is treated with excess of bromine water, it gives which of the following product?

  409. 409

    Liquid hydrocarbons are converted into gaseous hydrocarbons by:

  410. 410

    Ethane is obtained by electrolysing _:

  411. 411

    Consider the following structure of hydrocarbon which have double and triple bonds: Which of the following is the correct IUPAC name of above hydrocarbon?

  412. 412

    Which of the following is most reactive of all w.r.t electrophilic addition reaction?

  413. 413

    Which of the following reactions is used in the preparation of vegetable ghee from oil?

  414. 414

    f a triple bond is present between two carbons, then this class of compounds is called as _?

  415. 415

    What are Kekule's structures?

  416. 416

    Which one of the following is used for the artificial ripening of fruits?

  417. 417

    Which of the following are product of following reaction in the presence of diffused sunlight? CH4 + Cl2 →?

  418. 418

    Which of the following is an example of alicyclic hydrocarbon?

  419. 419

    Which of the following reactions is/are shown by alkynes?

  420. 420

    Which of the following reaction is/are shown by ethene?

  421. 421

    Which of the following is the most reactive hydrocarbon (w.r.t electrophilic addition)?

  422. 422

    The structural formula of the following given compound 4-Ethyl-3.4-dimethylheptane is:

  423. 423

    The correct name according to IUPAC of the following alkene is: H3C CH = CH - CH2 = CH2

  424. 424

    Which one of the following statements is incorrect about addition and substitution reaction?

  425. 425

    Cyclohexane is an example of:

  426. 426

    According to atomic orbital treatment of benzene, all of the following statements are correct about benzene EXCEPT:

  427. 427

    Consider the following reaction

  428. 428

    When acetylene is passed under pressure over an organo-nickel catalyst at 70°C _ is formed?

  429. 429

    When ethyne is treated with ammonical Cu2Cl2 solution, then ppt of dicopper acetylide are formed. The colour of ppt is?

  430. 430

    Acetaldehyde is prepared b-ty he reaction of ethyne with water in the presence of HgSO4/H2SO4 at 75°C. Number of steps involved in this reaction are:

  431. 431

    On oxidation of ethyne with strong alkaline KMnO4 solution, the final product formed is:

  432. 432

    Kolbe's electrolytic method is used to prepare ethyne. Which of the following salts of carboxylic acid is used for this purpose?

  433. 433

    Which of the following methods is used to prepare ethyne on the industrial scale by?

  434. 434

    When different alkenes are treated with hot concentrated KMInO4 solution, different products are obtained. Which of the following alkenes produces two moles ketone?

  435. 435

    All of the following methods explain stability of benzene EXPECT:

  436. 436

    o- and p- directing groups have all of the following properties EXPECT:

  437. 437

    Benzene cannot undergo:

  438. 438

    The most important addition reaction of alkenes forms the basis of the plastic industry. Addition polymerization is such process in which smaller molecules (monome) repeatedly combine to form large molecular having greater molar mass (polymer) as shown:

  439. 439

    When toluene is treated with chlorine in the presence of sunlight, which of the following is ultimate product?

  440. 440

    Among the followings the compound that can be most readily nitrated is:

  441. 441

    Which property of benzene may be directly attributed to the stability associated with its delocalized pi-electrons?

  442. 442

    Consider the following reaction: H2C = CH2 + HBr -> H3C - CH2Br The mechanism of reaction is:

  443. 443

    Alkanes are used as fuels. We burn them for many reasons. Which of the following is not its use?

  444. 444

    Aromatic compounds burn with sooty flame because:

  445. 445

    Which of the following alkenes does not follow Markownikov's rule?

  446. 446

    A hydrocarbon, which is akhrithid at room temperature, decolourizes aqueous bromine. Which could be the molecular formula of the compound?

  447. 447

    Which of the following tests is not used to distinguish between alkanes and alkenes?

  448. 448

    Which of the following is correct order of ease of dehydration of alcohols?

  449. 449

    All the following are dehydrating agents EXCEPTS:

  450. 450

    β-elimination is competitive to nucleophilic substitution reaction. It. has all of the following conditions for reaction as compared to nucleophilic substitution reaction EXCEPT:

  451. 451

    Benzene reacts with acetyl chloride in the presence of catalyst AICI3 to give:

  452. 452

    Nitrobenzene may be prepared by reacting benzene with a mixture of conc. H2SO4 and conc. HNO3 at 55°C. Which of the following best explains the role of conc. H2SO4?

  453. 453

    Chlorination of methane is believed to proceed through free radical mechanism. Which of the following is propagation step?

  454. 454

    Methane when burnt in the presence of metallic catalyst (Cu), at high temperature (400°C) and pressure (200atm), which of the following is the ultimate product?9

  455. 455

    The reaction of chlorine with methane is carried out in the presence of diffused sunlight. What is function of the light?

  456. 456

    X→ CI2/FeCI3 → Y→ HNO3+H2 SO4 → Z, Z in this reaction is possibly

  457. 457

    Which group deactivates the benzene ring?

  458. 458

    Most reactive compound among the following:

  459. 459

    The oxidation of toluene by acidified KMnO4 produces

  460. 460

    Benzoic acid is the main product when _is oxidized by acidified K2Cr2O7

  461. 461

    Benzoic acid is the only oxidation product along with formation H2O and CO2, of an organic compound A, when A is treated with acidified potassium dichromate, A is

  462. 462

    X is decolourized when alkyl benzene are readily oxidized to benzoic acid, X is

  463. 463

    This reaction is an example of:

  464. 464

    The conversion of benzene into cyclohexane is_

  465. 465

    Which of the following is produced by the action of CH3CI on benzene in presence of AICI3 followed by oxidation in the presence of acidified KMnO4 give

  466. 466

    What is required other than anhydrous AICI3 when toluene is prepared by Friedal craft reaction?

  467. 467

    How many π electrons are there in benzene to form delocalized electronic cloud?

  468. 468

    The resonance energy of benzene is

  469. 469

    Total number of hybrid orbitals of all the carbon atoms in benzene are:

  470. 470

    Which of the following compound reacts with sodium to yield hydrogen gas

  471. 471

    Acetylene gives_precipitates with AgNO3 in ammonium hydroxide solution

  472. 472

    Acetone is prepared by the hydration of

  473. 473

    Which of the following is most reactive to give electrophilic addition reactions

  474. 474

    Which of the following is not acidic in nature

  475. 475

    The only alkyne which gives an aldehyde upon the addition of water

  476. 476

    Baeyer's reagent is used in the laboratory for

  477. 477

    Which of the following is mono-ene

  478. 478

    In addition of HCI to CH3CH=CH2, which one will be added first:

  479. 479

    The test for unsaturation of organic compounds is carried out by treating alkenes with 1% dilute alkaline KMnO4 solution. The colour of KMnO4 is discharged with the formation of

  480. 480

    The preparation of vegetable ghee involves

  481. 481

    Hydroxylation of alkenes produce

  482. 482
    Balochistan MDCAT 2011

    Which of the following test can be used for distinguishing an alkane and an alkene

  483. 483

    Which of the following will decolorize bromine water?

  484. 484

    What type of reaction occurs between ethene and hydrogen?

  485. 485

    Which of the following is not used for the dehydration of alcohols?

  486. 486

    Dehydrohalogenation of RX occurs in the presence of

  487. 487

    Elimination of a halogen atom together with a hydrogen atom from an alkyl halide produces:

  488. 488

    Dehydration of alcohols with conc. H2SO4 at 180°C gives:

  489. 489

    The ease of dehydration of alcohols to produce alkenes of the order

  490. 490

    Halogenation of alkane is believed to proceed through

  491. 491

    The most probable products are _when CI2 is supplied in very high excess to react with CH4:

  492. 492

    The termination step in chlorination of methane in presence of diffused sun light is

  493. 493

    Propagation of free radical mechanism takes place by the

  494. 494

    The extent of halogenation of alkanes depends upon the factors:

  495. 495

    Consider the following reaction:

  496. 496

    A carbon, hydrogen and oxygen atoms containing organic compound (A), on reaction with an excess of CH3MgI, gives a gas (X) whose volume under STP conditions is found to be 89.6litre. Find the number of hydroxyl groups in the compound (A):

  497. 497

    Benzene on reaction with isolbutyl chloride in the presence of AlCl3 gives:

  498. 498

    When isobutane is monochlorinated in the presence of ultra-violet light, the product obtained in higher yield is:

  499. 499

    The compounds 1-butyne and 2-butyne can be distinguished by using:

  500. 500

    The ozonolysis of an olefin gives propanone. The olefin is: