Chemistry of Hydrocarbons
MDCAT • Chemistry
500 MCQs — Click "Reveal" to see the correct answer
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1NUMS MDCAT 2024The most readily sulphonated compound is:
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2Identify the alkene which gives only one type of aldehyde upon ozonolysis:
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3Balochistan MDCAT 2024When a hydrogen atom of an alkane is removed, the resulting group is called:
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4Benzene when reacts with chlorine in presence of sunlight gives additional product, i.e.:
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5In alkane series, all the linkages between carbon atoms are which type of bonds?
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6Which is regarded as the simplest and the parent member of aromatic class of compounds?
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7Balochistan MDCAT 2024Natural gas consists mainly of:
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8Sindh MDCAT 2024The density of benzene is:
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9When chlorobenzene reacts with sodium hydroxide at 350°C and 150 atmospheric pressure, it gives formation of:
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10Sindh MDCAT 2024The bond length between C-C in benzene is:
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11When an unsymmetrical alkene undergoes addition reactions, the negative part of the attacking reagent is added to that double-bonded carbon atom which contains:
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12The carbon atom carrying positive charge and attached to three other atoms or groups is called:
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13Addition of HBr to isobutylene mainly gives:
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14The homolytic fission of C-H bond in an alkane results in:
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15FMDC MDCAT 2024 (Reconduct)Resonance energy of benzene is:
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16FMDC MDCAT 2024 (Reconduct)The common name of 1,3-dihydroxy benzene is:
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17
What is the IUPAC name of given compound? CH3-CH=CH-CH2-C≡CH
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18FMDC MDCAT 2024Which type of catalyst is used during electrophilic substitution reactions of benzene?
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19FMDC MDCAT 2024Which compound is used as a reference for calculating the extent of stability of benzene?
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20
The saturated alicyclic hydrocarbons have the general formula:
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21What will be the IUPAC name of neopentane?
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22
In Friedel Craft acylation, an acyl group is introduced in benzene ring in the presence of catalyst:
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23
Which of the following is an example of a substituent group which releases electrons to the benzene ring?
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24Balochistan MDCAT 2023The hydrocarbon which has isolated rings and is aromatic?
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25What do we mean by the term 'delocalized electrons' in benzene?
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26The acylium ion has a positive charge and acts as?
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27What of the following produces maleic anhydride on oxidation?
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28Oxidation of toluene by KMnO4 gives the product:
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29Benzene is subjected to (1) Alkylation (2) Nitration (3) Oxidation. The product is:
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30
When benzene reacts with isopropyl chloride in the presence of AlCl3 as Lewis acid (Friedel Craft Acylation), the product formed is isopropyl benzene. What is this reaction called?
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31
What hybridization is present on carbon atoms in Ethyne C2H2?
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32
Among the following hydrocarbons, which one has acidic hydrogen?
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33
Identify the electrophile called as acylium ion:
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34
Which one of the following is not a meta directing group?
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35FMDC MDCAT 2023Which compound is least reactive?
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36If both double and triple bonds are present, then the ending given to the root is:
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37FMDC MDCAT 2023
Which of the following will not give substitution reaction?
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38Under suitable conditions, alkanes cannot undergo which reactions?
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39The resonance energy of benzene is how many KJ/mole more stable than expected?
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40Which isomer of pentane has least melting and boiling point?
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41
IUPAC name of the following compound CH3-(CH3)2-C(CH3)3 is:
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42Balochistan MDCAT 2022Michael Faraday discovered benzene in the gas formed from?
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43
Benzene also undergoes electrophilic substitution when treated with fuming sulphuric acid for several hours. The electrophile in this reaction is?
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44Benzene is subjected to alkylation, nitration & oxidation. The product is:
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45Isopropyl benzene is also called:
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46
The electrophile which is considered to be the active agent in the nitration of benzene is:
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47
Propyne reacts with aqueous sulphuric acid in the presence of HgSO4 to form:
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48Which of the following compounds has highest boiling point?
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49Reactivity order of halogen acid is:
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50FMDC MDCAT 2023The correct order of reactivity of hydrocarbons is:
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51
Consider the chlorination of CH4, the attack of chlorine free radical on CH4 to form methyl free radical occurs in?
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52
Alkyl benzene is formed when benzene is treated with an alkyl halide in the presence of anhydrous AlCl3. Identify the type of reaction.
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53
Which of the following acts as electrophile during nitration of benzene?
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54Which of the following is marsh gas?
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55Benzene does not show:
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56Ethene has how many pi bonds?
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57
When CH3 is attached with the benzene ring, it makes the ring:
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58Acetophenone can be formed by which of the following reaction of benzene?
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59PMDC MDCAT 2020
Electrophile in sulphonation of benzene is:
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60Treatment of ethene with cold sulphuric acid followed by reaction with boiling water yields:
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61
An olefin 'X' on ozonolysis gives CH3CH2COCH3 and CH3COCH3. The IUPAC name of X is:
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62
A gas decolorizes alkaline KMnO4 solution but does not give any PPT with ammonical AgNO3:
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63
Select meta directing group of the following:
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64
The correct order of the reactivity of hydrocarbon given below is:
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65Which of the following compounds reacts slower than benzene in electrophilic substitution reaction?
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66
Which catalyst is used in oxidation of benzene ring?
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67Acetone can be obtained by ozonolysis of:
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68
Order of reactivity of halogen toward alkane is:
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69Homolysis of a covalent bond yields a very reactive species with incomplete octet in its valence shell. What is this species?
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70
In the reaction sequence: H3C-CH2 + Br2 → A, then A + alc.KOH → B. The end product is an unsaturated hydrocarbon. Identify the nature of reaction in the two steps.
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71
Which of the options show all possible products of combustion of Butene?
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72
In Friedel-Craft's Chlorination of Benzene, Iron III chloride acts as a catalyst. Which is the initial reaction in the generation of an electrophile?
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73
Which one of the following acts as an electrophile in the electrophilic substitution of benzene with bromine?
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74
Bromination of alkene is shown in the following reaction. The reaction is used for:
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75Reaction mechanism of alkanes with halogens is known as:
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76
Among the following, which one has electron withdrawing effect?
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77
For halogenation of benzene, which reagent is used?
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78
Which of the following species are 3,5 (meta) directing groups when a second group is introduced into the benzene ring? I = -NH2,
II = -CHO,
III = -COOH,
IV = CH3
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79
The mechanism of reaction of benzene with bromine in the presence of FeBr3 follows the:
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80
Which one of the following is a powerful electrophile used to attack on the pi electrons of benzene ring?
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81The introduction of R-C=O group in benzene is called:
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82Ethene on polymerization gives the product polyethene. This reaction may be called as:
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83
Benzene in presence of AlCl3 gives acetophenone when reacts with:
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84
The substitution of -H group by -NO2 group in benzene is called:
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85
Ethyne molecule is formed when two carbon atoms joined together to form a sigma bond only by:
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86
The introduction of NO2 group in the benzene ring is called nitration. The nitration of benzene takes place when it is heated with a 1:1 mixture at 50-55°C of:
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87When hydrogen atom is removed from benzene, the group left is called:
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88UHS MDCAT 2008
In this process, higher hydrocarbons can be cracked at lower temperature and lower pressure:
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89UHS MDCAT 2008
In which of the following is carbon double bonded with itself?
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90UHS MDCAT 2008
Alkanes containing _ carbon atoms are waxy solids.
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91UHS MDCAT 2009
Which compound is the most reactive one?
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92UHS MDCAT 2009
During nitration of benzene, the active nitrating agent is:
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93UHS MDCAT 2010
The introduction of NO2 group in benzene ring is called ‘Nitration’. The nitration of benzene takes place when it is heated with a 1:1 mixture of _ at 50-55.
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94UHS MDCAT 2010
Symmetrical alkanes can be produced by:
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95UHS MDCAT 2010
Ethyne molecule is formed when two carbon atoms joined together to form a sigma bond by:
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96UHS MDCAT 2010
A gasoline of higher octane number can be obtained by:
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97UHS MDCAT 2011
The substitution of a '-H' by '-NO2' group in benzene is called:
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98UHS MDCAT 2011
Benzene in the presence of AlCl3 produces acetophenone when reacts with:
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99UHS MDCAT 2011
Hydrogenation of unsaturated oils is done by using:
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100UHS MDCAT 2012
The introduction of the following group in benzene is called:
O
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R - C -
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101UHS MDCAT 2015
The IUPAC name of the given compound is:
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102UHS MDCAT 2015
Which one of the following is a powerful electrophile used to attack on the electrons of a benzene ring?
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103UHS MDCAT 2016
It is the general formula of:
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104UHS MDCAT 2016
Which one of the following is an appropriate structure for the product of bromination?
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105UHS MDCAT 2016
Skeletal formula of a hydrocarbon is given below. What is the IUPAC name of the compound?
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106UHS MDCAT 2016
Which one of the following reactions shows the combustion of a saturated hydrocarbon?
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107UHS MDCAT 2017
What will be the product of the reaction given below?
CH3
\
C = O + HCN (in presence of NaCN /HCl) Y?
/
C2H5
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108UHS MDCAT 2017
The reaction of bromine with benzene in the presence of FeBr3 follows the mechanism of:
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109UHS MDCAT 2017
When benzene reacts with acetyl chloride (CH3COCl) in the presence of AlCl3, acetophenone is formed. The electrophile in this reaction will be:
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110UHS MDCAT 2017
Which of the following are 3,5 (meta) directing groups when second group is induced in them:i) -NH3
ii) -CHO iii) -COOH iv) -CH3
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111UHS MDCAT 2017
Immediate product formed when propanoyl chloride reacts with benzene is:
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112UHS MDCAT 2017
Which one of the following is used as a typical catalyst for catalytic cracking?
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113UHS MDCAT 2017 (Reconduct)
How many pi bond(s) are there in ethene?
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114UHS MDCAT 2017 (Reconduct)
Chlorination and Bromination mostly uses:
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115UHS MDCAT 2017 (Reconduct)
What should be the temperature and pressure respectively for catalytic cracking:
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116UHS MDCAT 2018
Bromination of alkene is shown in the following reaction. This reaction is used for:
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117UHS MDCAT 2018
Which of the following acts as an electrophile in the electrophilic substitution of benzene with bromine?
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118UHS MDCAT 2018
Butane molecules can have a maximum number of isomers.
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119UHS MDCAT 2018
The species which are produced by heterolytic bond breaking and can act as electron pair donors are known as:
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120UHS MDCAT 2019
The names of functional groups in the following compound X are:
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121UHS MDCAT 2019
Which derivative of benzene shows maximum reactivity in electrophilic substitution reactions?
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122UHS MDCAT 2019
Alkenes undergo:
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123UHS MDCAT 2019
Which of the following molecule shows cis-trans isomers?
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124UHS MDCAT 2022
The ratio of sigma to pi electrons in benzene is?
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125UHS MDCAT 2022
Consider the chlorination of methane, the attack of chlorine free radical on methane form methyl free radical occurs in?
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126UHS MDCAT 2022
Which of the following compound is more acidic?
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127UHS MDCAT 2022
Three alternate single and double bonds in benzene are called?
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128UHS MDCAT 2022
Alkylbenzene is formed when benzene is treated with an alkyl halide In the presence of anhydrous aluminum chloride, Identify the type of reaction.
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129UHS MDCAT 2022
What is the number of isomers of a hydrocarbon having a molecular formula, C4H8?
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130UHS MDCAT 2023
Identify which method is used to prepare Alkynes?
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131UHS MDCAT 2023
Propanone can be prepared from propyne by:
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132UHS MDCAT 2023
When 2-bromopropane reacts with Sodium ethoxide, the major product is/are?
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133UHS MDCAT 2023
Alkylbenzene is formed when benzene is treated with an alkyl halide in the presence of anhydrous aluminum chloride. Identify the type of reaction.
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134UHS MDCAT 2023
Under suitable conditions alkanes cannot undergo _ reactions?
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135UHS MDCAT 2023
The addition reaction of 2-butene with HBr produces?
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136UHS MDCAT 2023
Which of the following reagents can be used to distinguish between 1-Pentyne and 2-Pentyne?
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137UHS MDCAT 2024
Which one of the following represents nitration of benzene correctly?
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138UHS MDCAT 2024
In Friedel Craft acylation an acyl group is introduced in benzene ring in the presence of catalyst:
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139UHS MDCAT 2024
Which of the following is an example of substituent group which release electrons to benzene ring:
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140PMDC MDCAT 2025
In propene pi-bond is formed by sideway overlap of:
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141PMDC MDCAT 2025
Chlorination of benzene in the presence of iron (III) chloride involves mechanism of:
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142PMDC MDCAT 2025
Which one of the following is not a characteristic of benzene?
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143PMDC MDCAT 2025
What is general requirement for free radical substitution reaction of ethane and halogen?
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144PMDC MDCAT 2025
Terminal alkynes show acidic character due to:
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145
Benzene — (Cl2 / FeCl3) → Y
— (HNO3 + H2SO4) → Z
Z in this reaction is possibly:
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146The oxidation of toluene by acidified KMnO₄ produces
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147Benzoic acid is the main product when ______ is oxidized by acidified K₂Cr₂O₇
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148Benzoic acid is the only oxidation product along with formation of H₂O and CO₂ of an organic compound A, when A is treated with acidified potassium dichromate, A is
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149X is required when alkyl benzenes are readily oxidized to benzoic acid. X is
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150
This reaction is an example of:
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151The conversion of benzene into cyclohexane is
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152Which of the following is produced by the action of CH₃Cl on benzene in presence of AlCl₃ followed by oxidation in the presence of acidified KMnO₄?
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153What is required other than anhydrous AlCl₃, when toluene is prepared by Friedel-Crafts reaction?
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154How many π electrons are there in benzene to form delocalized electronic cloud:
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155Acetylene gives precipitates with AgNO₃ in ammonium hydroxide solution
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156The only alkyne which gives an aldehyde upon addition of water
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157In addition of HCl to CH₃CH=CH₂, which one will be added first:
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158In which addition reaction Markownikov's rule is not obeyed:
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159The test for unsaturation of organic compounds is carried out by treating alkenes with dilute alkaline KMnO₄ solution. The colour of KMnO₄ is discharged with the formation of
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160Dehydration of alcohols with conc. H₂SO₄ at 180°C gives:
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161The ease of dehydration of alcohols to produce alkenes is of the order:
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162The most probable products are when Cl₂ is supplied in very high excess to react with CH₄:
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163
The 2nd step in chlorination of methane in presence of diffused sun light is
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164Oxidation of benzene is possible by
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165Sigma bonds in alkanes are
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166Which of the following is true for halogenation of CH₄?
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167Cis-alkene is obtained from alkynes by
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168Which of the following is true for hydrogenation reaction?
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169
General formula of alkyl group is
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170The addition of unsymmetrical reagent to an unsymmetrical alkene takes place in accordance with
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171Position of double bond in alkenes can be determined by
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172Which of the following compounds is more acidic?
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173The number of sigma and pi bonds in 2-butene are
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174UHS MDCAT 2019
Which of the following reactions is used for the production of alcohols on industrial scale?
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175UHS MDCAT 2018
Which compound is obtained by the elimination of bromopropane?
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176
An activating substituents group activate
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177
Which of the following is Ortho para directing group
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178
The compound that can be most readily sulphonated is
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179
Which of the following substitution of benzene is Ortho para in electrophilic substitution and Ortho para in nucleophilic substitution
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180
Choose the substituent that will direct meta addition on a benzene ring.
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181
Which of the following substituents is electron-withdrawing when added to a benzene ring?
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182
A deactivated substituents groups directs
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183
The ortho and para-hydrogens possesses:
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184
The ortho/para directing group among the following is
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185
Which of the following is the strongest ortho, para directing group :
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186
Which catalyst is used in Friedel-craft alkylation reaction
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187
Which of the following aromatic compounds undergo Friedel-Crafts alkylation with methyl chloride and aluminum chloride?
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188
What is the electrophile in the acylation of benzene
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189
Which of the following is the most activating in electrophilic aromatic substitution?
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190
What is the electrophile in the electrophilic substitution reaction of benzene using oleum and conc. H2SO4
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191
This can be a halide in the Friedel Crafts reaction
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192
Which of the following will not easily undergo Friedel Crafts reaction?
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193
In Friedel Craft, Alkylation AICI3 is used to generate
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194
Reacting bromine with benzene in the presence of sunlight will result in
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195
Acetophenone is a
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196
Benzene does not undergo
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197
During sulphonation of benzene, H2SO4 generates the electrophile
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198
Benzene is heated in air with V2O5 at 450C it undergoes
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199
The preparation of benzene from acetylene can also be said as
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200
What is required other than anhydrous AICI3 when toluene is prepared by Friedal craft reaction
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201
Replacement of hydrogen of benzene by alkyl group in the presence of alkyl halide & aluminium chloride is known as
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202
Which of the following groups are most likely to be o, p directing
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203
In Chlorination of benzene, which of the following acts as an electrophile?
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Nitration of benzene is carried out by which of the following reactive species?
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205
The hydrolysis of Benzenetrizonide will yield three moles of
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206
Chemical formula of Benzene is
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There are --- resonance structures available in Benzene.
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208
With the help of Cyclic polymerization, Benzene can be prepared from
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209
Physical state of benzene is
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210
Benzene melts at how many degree Celsius
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211
Benzene is soluble in
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212
Which of the following is not a physical property of the Benzene?
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213
Which is not a physical property?
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214
Aniline is a derivative of benzene which contains
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215
How many electrons are there in benzene to form delocalized electronic cloud
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216
What is the molecular formula of Benzenetriozonide
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217
Phenanthrene is a fused polycyclic compound contains _ benzene rings
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218
Ozonolysis of benzene produces
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p-bonds in benzene spread over all six carbons, hence they are called
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220
The molecular formula of toluene is
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Vanillin is used to give flavor in
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222
Chlorobenzene is one of the
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223
In most of the organic compounds, the group found is
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Which is fused cyclic aromatic compound
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225
Chlorination of toluene in the presence of sunlight produces
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226
The oxidation reaction of alkyne (ethyne) with alcoholic potassium permanganate produce
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227
The major alkyne, acetylene compound is produced by which among the following application on natural gas
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228
When ethyne is passed through a red hot tube, _ is formed
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229
The transformation into carboxylic acids of the alkynes takes place with the help of which among the following reagents
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230
Alkynes cannot be prepared from
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Ethyne and Ethane can be separated from a mixture by passing it through
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232
1-butyne and 2-butyne can be identified by using which of the following reagents
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233
Which among the following alkynes is used as a rocket fuel
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234
Which among the following product is formed when ethyne undergoes reaction with HgSO4 and H2SO4
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235
Acetylene is oxidised by KMnO4 to form
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236
The product formed in the reaction of ethyne with dilute H2SO4 and Hg2+ is
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237
Polymerisation product of propyne is
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238
The product formed in the reaction of propyne with dilute H2SO4 and HgSO4 is
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239
Water can be added across a triple bond in the presence of
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240
When propyne is treated with dilute H2SO4 in presence of HgSO4 the major product will be:
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241
Acetylene is obtained by the electrolysis of
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242
When ethyne is subjected to ozonolysis of, what is the end product
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243
Ethyne on oxidation with alcoholic KMnO4 forms _
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244
Which of the following is used for welding?
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245
Alkyne are slightly in nature
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246
Alkynes have a _ bonding strength
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247
Alkynes have a _ boiling point than alkanes
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248
Alkynes are slightly _ in nature.
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249
The boiling and melting points of alkynes -------- as their molecular structure becomes more complex.
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250
The first three alkynes have state of matter
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251
Unsaturated carbon with how many bonds at the carbon site is known as alkynes.
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252
The 'sp' hybridization is present in:
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253
Write the IUPAC name of the following alkyne compound
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254
Are alkynes more reactive than alkenes
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255
What is a general formula of alkynes
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256
Acetylene contains:
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257
Different members of alkynes are named in the form of _ derivatives
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258
The nomenclature of alkynes is quite similar to the nomenclature of _
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259
Terminal alkynes and internal alkynes are the _forms of alkynes.
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260
Tetrahydroxy ethane loses two water molecules to form
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261
Glyoxal formed by loss of two water molecules by tetrahydroxy ethane oxidizes to
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262
Alkynes show _ reactions
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263
The first member of the alkyne homologous series' is
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264
Alkanes, alkenes and alkynes is the combination of which of the following elements:
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265
Oxy-acetylene torches can produce temperature as high as
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266
What type of reaction do alkynes undergo across the triple bond
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267
Which of the following are saturated hydrocarbons?
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268
Acetylene is also called
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269
Which of the following compounds react most readily with Br(g)
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270
Which of following is not colorless
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271
Which of the following statement is true regarding the reactivity order in order to form alkyl halides
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272
Addition reaction of hydrogen Bromide to the unsymmetrical alkene follows _
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273
In Alkenes the Carbon atoms are connected to each other by a
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274
What causes the red color of tomatoes?
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275
Addition of hydrogen to ethene forms
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276
When bromine water is added to an alkene, the product is
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277
When two carbon atoms share three electron pairs then they form
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278
The catalyst which is used to break hydrocarbons is
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279
The lower molar mass of hydrocarbons has increased
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280
Alkenes mostly follow the reaction of
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281
If ethene is a reactant, then the product will be
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282
Under certain conditions, the ethene molecule reacts to give
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283
The double bond in ethene is formed from a
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284
Addition reaction of hydrogen Bromide to the unsymmetrical alkene follows _ Alkenes can be oxidized by the help of a powerful oxidizing agent, acidified
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285
Alkenes show _ isomerism Unsaturated oils become partially saturated when they are reacted with
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286
Hydrocarbons containing double bonds are called
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287
C=C has a high electron density area hence it is
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288
Alkenes (C=C) are known to be _ hydrocarbon
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289
C5-C15 members of alkenes are
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290
How much ethene is required for the ripening of 1 kg of tomatoes
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291
Which of the following processes involves the addition of hydrogen molecule across carbon-carbon multiple-bond?
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292
Higher members of alkenes are
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293
Due to the presence of double bonds, alkenes are
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294
Ethene is prepared from chloroethane this is an example of a reaction _
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295
At which temperature and pressure ethene is polymerized to polyethylene and polyurethane?
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296
In this process small organic molecules (monomer) combine together to form Larger molecules known as
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297
The reduction of ozonides produces
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298
Ozone O3 is highly reactive allotropic form of
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299
The presence of unsaturation is also detected by
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300
The Baeyer's reagent act as
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301
The Baeyer's reagent has colour of?
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302
Most alkenes are hydrogenated over Raney nickel at about
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303
Raney nickel is a spongy form of _ . It has porous surface
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304
Catalytic hydrogenation of alkenes is used in industry for the manufacturing of
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305
The heat of hydrogenation of most alkene is about - for each double bond present in a molecule
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306
Baeyer's reagent is
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307
The presence of double and triple bond in a compound is the sign of
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308
Alkenes show weakly polar property because of
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309
Alkenes are soluble in
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310
C5 to C15 are........
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311
Which members of alkene are Gases at room temperature
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312
CH2=CH-CH=CH2 the name of this compound
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313
In alkene the numbering begins from the end nearest to the
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314
Designate the location of double bond by using the number of the.....of the double bond as a prefix
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315
Longest continuous chain of alkene containing parents chain of
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316
The alkene are given name by alkanes by changing the identical 'ane' to
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317
Alkene containing two double bond are known as
-
318
The general formula for alkene
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319
The simplest olefins is
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320
Alkenes are also known as
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321
Alkene has ...... hydrogen atom less than the corresponding saturated hydrocarbons
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322
N2H4//KOH is used as...... in wolf kishner reduction
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323
The general formula having by alkanes is
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324
In alkane the carbon is bonded by
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325
Unsaturated hydrocarbons are known asAlkanes
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326
Saturated hydrocarbons are also known as
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327
When methane reacts with Cl2 in the presence of diffused light, the product obtained are:
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328
Beta and beta prime dicholoro ethyl sulphide is commonly known as
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329
Preparation of vegetable ghee involves
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330
In Clemmensen reduction Zn-Hg/HCl and in in Wolf kishner reduction N2H4/KOH is used to generate
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331
Alkyl halides react in anhydrous ether with magnesium to form alkyl magnesium halides known as
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332
Wolf kishner 's readuction reduces aldehyde into
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333
Clemmensen reduction is the reduction of
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334
Kolbe's electrolytic method takes place in the presence of
-
335
Decarboxylation of monocarboxylic acid reaction of alkanes takes place in the elimination of
-
336
Addition of hydrogen accompanied by a bond cleavage is called
-
337
Which catalyst is used in hydrogenolysis
-
338
Which cleavage takes place in hydrogenolysis
-
339
Which cleavage takes place in hydrogenation
-
340
Sabatier -sendern's reaction can be used to prepare
-
341
The hydrogenation Reactions of alkanes at 200°C-300°C temperature, takes place in the presence of
-
342
The addition of hydrogen in alkenes or alkynes in the presence of nickel at 200-300°C yields alkanes is called
-
343
The alkanes has geometry
-
344
Each carbon atom in alkane has hybridization
-
345
Alkanes are also known as
-
346
Alkanes are simplest organic compounds made up of carbon and…… only
-
347
The formula of dicholoro methane is
-
348
Which type of reaction are given by alkanes
-
349
Alkanes are non -polar they are soluble in
-
350
Find the compound with the highest boiling point among the following
-
351
Paraffin wax is
-
352
If we remove one hydrogen atom from alkane the rest of group is called
-
353
The name marsh gas was given to:
-
354
The self linking property of carbon atom is called
-
355
The reaction of propane with bromine is called?
-
356
An alkane with 7 carbon atoms contains _ hydrogen atoms.
-
357
Find the alkane (C5H12), which will give only one type of monohalogenated compound
-
358
The substituent in the chain is named by replacing the "ane" in the alkanes by _
-
359
Identify the smallest alkane which can form a ring structure (cycloalkane)?
-
360
Identify the correct alkane name for the molecular formula C30H62
-
361
Saturated hydrocarbons are otherwise referred as _
-
362
Which among the following is not an alkane isomer with 6 carbon atoms?
-
363
Select the minimum number of carbon atoms, a molecule must possess so as to be regarded as a higher alkane.
-
364
Identify the simplest alkane
-
365
Select the incorrect statement regarding alkanes.
-
366
When different alkenes are treated with hot concentrated KMnO4 solution, different products are obtained. Which of the following alkenes produces two moles of carboxylic acids?
-
367
Which one of the following is a powerful electrophile used to attack On the electrons of benzene ring?
-
368
Skeletal formula of an organic compound iv given below: It is a hydrocarbon. IUPAC name of the compound is:
-
369
Chlorination and bromination of alkanes can be done mostly in the presence of:
-
370
In β-elimination reaction, _ is used:
-
371
Structural formula of 2,3,4-Trimethylpentane is:
-
372UHS MDCAT 2017 (Reconduct)
Catalytic oxidation of alkanes results in the formation of _:
-
373UHS MDCAT 2017 (Reconduct)
For halogenation of benzene, which reagent is used:
-
374
Consider the following structure: Which one of the following is an appropriate name of above compound?
-
375
o- and p-nitrophenol are formed by the reaction of _ with phenol at 25°C:
-
376
Phenol undergoes ionization to become more stable by reacting with which of the following chemical species?
-
377
The reaction of benzene with bromine in the presence of FeBr3 follows the mechanism of _ reaction:
-
378
4-Bromobut-1-ene is the name of which among the following alkenes?
-
379
When benzene reacts with acetyl chloride (CH3COCI) in the presence of AlCl3, acetophenone is formed. The electrophile in this reaction will be:
-
380
Which of the following species are 3,5 (meta) directing groups when second group is introduced into the benzene ring: I = -NH2 II = -CHO III = -COOH IV = -CH3
-
381UHS MDCAT 2015
The given three hydrocarbons are:
-
382UHS MDCAT 2015
Order of reactivity of alkenes with hydrogen halide is:
-
383UHS MDCAT 2013
What is the product formed when propene reacts with HBr?
-
384UHS MDCAT 2014
Addition of unsymmetrical reagent to an unsymmetrical alkene is governed by:
-
385
Bakelite is formed when phenol react with which of the following reactant?
-
386
In hich of the following carbon is double bonded with itself?
-
387
Butyne and 2-Butyne can be identified by using which of the following reagents?
-
388
Hydrogen passed through phenol at 150°C in the presence of _ catalyst gives cyclohexanol:
-
389UHS MDCAT 2008
Ten moles of hydrogen are allowed to react with 6 moles of oxygen. How much water will be obtained from reaction on complete consumption of one gas?
-
390
Alkanes containing _ carbon atoms are waxy solids:
-
391
Alkanes mostly give _?
-
392
The conversion of n-hexane to benzene by heating is called:
-
393
Which of the following statements is/are correct?
-
394
The simplest member of organic compounds is?
-
395
Benzene is extra stable because of _?
-
396
Bomine/water reacts with phenol and decolorize orange colour and turns it to which of the coloured precipitate?
-
397
Ethylene bromide on treatment with Zn gives:
-
398
The reactivity of alkenes is due to the presence of?
-
399
What is the value of C-C bond length in benzene?
-
400
Formation of picric acid by phenols is called
-
401
In sp2 hybridization the orbital orientation is:
-
402
Alkynes show _ reactions.
-
403
Which of following shows maximum boiling point
-
404
Hydrocarbons are organic compounds with element _:
-
405
How carboxylic acid group attached to the benzene ring affect its reactivity?
-
406
Ethyne on oxidation with strong alkaline KMnO4 forms:
-
407
Which one of the following is correct structure of benzene?
-
408
When phenol is treated with excess of bromine water, it gives which of the following product?
-
409
Liquid hydrocarbons are converted into gaseous hydrocarbons by:
-
410
Ethane is obtained by electrolysing _:
-
411
Consider the following structure of hydrocarbon which have double and triple bonds: Which of the following is the correct IUPAC name of above hydrocarbon?
-
412
Which of the following is most reactive of all w.r.t electrophilic addition reaction?
-
413
Which of the following reactions is used in the preparation of vegetable ghee from oil?
-
414
f a triple bond is present between two carbons, then this class of compounds is called as _?
-
415
What are Kekule's structures?
-
416
Which one of the following is used for the artificial ripening of fruits?
-
417
Which of the following are product of following reaction in the presence of diffused sunlight? CH4 + Cl2 →?
-
418
Which of the following is an example of alicyclic hydrocarbon?
-
419
Which of the following reactions is/are shown by alkynes?
-
420
Which of the following reaction is/are shown by ethene?
-
421
Which of the following is the most reactive hydrocarbon (w.r.t electrophilic addition)?
-
422
The structural formula of the following given compound 4-Ethyl-3.4-dimethylheptane is:
-
423
The correct name according to IUPAC of the following alkene is: H3C CH = CH - CH2 = CH2
-
424
Which one of the following statements is incorrect about addition and substitution reaction?
-
425
Cyclohexane is an example of:
-
426
According to atomic orbital treatment of benzene, all of the following statements are correct about benzene EXCEPT:
-
427
Consider the following reaction
-
428
When acetylene is passed under pressure over an organo-nickel catalyst at 70°C _ is formed?
-
429
When ethyne is treated with ammonical Cu2Cl2 solution, then ppt of dicopper acetylide are formed. The colour of ppt is?
-
430
Acetaldehyde is prepared b-ty he reaction of ethyne with water in the presence of HgSO4/H2SO4 at 75°C. Number of steps involved in this reaction are:
-
431
On oxidation of ethyne with strong alkaline KMnO4 solution, the final product formed is:
-
432
Kolbe's electrolytic method is used to prepare ethyne. Which of the following salts of carboxylic acid is used for this purpose?
-
433
Which of the following methods is used to prepare ethyne on the industrial scale by?
-
434
When different alkenes are treated with hot concentrated KMInO4 solution, different products are obtained. Which of the following alkenes produces two moles ketone?
-
435
All of the following methods explain stability of benzene EXPECT:
-
436
o- and p- directing groups have all of the following properties EXPECT:
-
437
Benzene cannot undergo:
-
438
The most important addition reaction of alkenes forms the basis of the plastic industry. Addition polymerization is such process in which smaller molecules (monome) repeatedly combine to form large molecular having greater molar mass (polymer) as shown:
-
439
When toluene is treated with chlorine in the presence of sunlight, which of the following is ultimate product?
-
440
Among the followings the compound that can be most readily nitrated is:
-
441
Which property of benzene may be directly attributed to the stability associated with its delocalized pi-electrons?
-
442
Consider the following reaction: H2C = CH2 + HBr -> H3C - CH2Br The mechanism of reaction is:
-
443
Alkanes are used as fuels. We burn them for many reasons. Which of the following is not its use?
-
444
Aromatic compounds burn with sooty flame because:
-
445
Which of the following alkenes does not follow Markownikov's rule?
-
446
A hydrocarbon, which is akhrithid at room temperature, decolourizes aqueous bromine. Which could be the molecular formula of the compound?
-
447
Which of the following tests is not used to distinguish between alkanes and alkenes?
-
448
Which of the following is correct order of ease of dehydration of alcohols?
-
449
All the following are dehydrating agents EXCEPTS:
-
450
β-elimination is competitive to nucleophilic substitution reaction. It. has all of the following conditions for reaction as compared to nucleophilic substitution reaction EXCEPT:
-
451
Benzene reacts with acetyl chloride in the presence of catalyst AICI3 to give:
-
452
Nitrobenzene may be prepared by reacting benzene with a mixture of conc. H2SO4 and conc. HNO3 at 55°C. Which of the following best explains the role of conc. H2SO4?
-
453
Chlorination of methane is believed to proceed through free radical mechanism. Which of the following is propagation step?
-
454
Methane when burnt in the presence of metallic catalyst (Cu), at high temperature (400°C) and pressure (200atm), which of the following is the ultimate product?9
-
455
The reaction of chlorine with methane is carried out in the presence of diffused sunlight. What is function of the light?
-
456
X→ CI2/FeCI3 → Y→ HNO3+H2 SO4 → Z, Z in this reaction is possibly
-
457
Which group deactivates the benzene ring?
-
458
Most reactive compound among the following:
-
459
The oxidation of toluene by acidified KMnO4 produces
-
460
Benzoic acid is the main product when _is oxidized by acidified K2Cr2O7
-
461
Benzoic acid is the only oxidation product along with formation H2O and CO2, of an organic compound A, when A is treated with acidified potassium dichromate, A is
-
462
X is decolourized when alkyl benzene are readily oxidized to benzoic acid, X is
-
463
This reaction is an example of:
-
464
The conversion of benzene into cyclohexane is_
-
465
Which of the following is produced by the action of CH3CI on benzene in presence of AICI3 followed by oxidation in the presence of acidified KMnO4 give
-
466
What is required other than anhydrous AICI3 when toluene is prepared by Friedal craft reaction?
-
467
How many π electrons are there in benzene to form delocalized electronic cloud?
-
468
The resonance energy of benzene is
-
469
Total number of hybrid orbitals of all the carbon atoms in benzene are:
-
470
Which of the following compound reacts with sodium to yield hydrogen gas
-
471
Acetylene gives_precipitates with AgNO3 in ammonium hydroxide solution
-
472
Acetone is prepared by the hydration of
-
473
Which of the following is most reactive to give electrophilic addition reactions
-
474
Which of the following is not acidic in nature
-
475
The only alkyne which gives an aldehyde upon the addition of water
-
476
Baeyer's reagent is used in the laboratory for
-
477
Which of the following is mono-ene
-
478
In addition of HCI to CH3CH=CH2, which one will be added first:
-
479
The test for unsaturation of organic compounds is carried out by treating alkenes with 1% dilute alkaline KMnO4 solution. The colour of KMnO4 is discharged with the formation of
-
480
The preparation of vegetable ghee involves
-
481
Hydroxylation of alkenes produce
-
482Balochistan MDCAT 2011
Which of the following test can be used for distinguishing an alkane and an alkene
-
483
Which of the following will decolorize bromine water?
-
484
What type of reaction occurs between ethene and hydrogen?
-
485
Which of the following is not used for the dehydration of alcohols?
-
486
Dehydrohalogenation of RX occurs in the presence of
-
487
Elimination of a halogen atom together with a hydrogen atom from an alkyl halide produces:
-
488
Dehydration of alcohols with conc. H2SO4 at 180°C gives:
-
489
The ease of dehydration of alcohols to produce alkenes of the order
-
490
Halogenation of alkane is believed to proceed through
-
491
The most probable products are _when CI2 is supplied in very high excess to react with CH4:
-
492
The termination step in chlorination of methane in presence of diffused sun light is
-
493
Propagation of free radical mechanism takes place by the
-
494
The extent of halogenation of alkanes depends upon the factors:
-
495
Consider the following reaction:
-
496
A carbon, hydrogen and oxygen atoms containing organic compound (A), on reaction with an excess of CH3MgI, gives a gas (X) whose volume under STP conditions is found to be 89.6litre. Find the number of hydroxyl groups in the compound (A):
-
497
Benzene on reaction with isolbutyl chloride in the presence of AlCl3 gives:
-
498
When isobutane is monochlorinated in the presence of ultra-violet light, the product obtained in higher yield is:
-
499
The compounds 1-butyne and 2-butyne can be distinguished by using:
-
500
The ozonolysis of an olefin gives propanone. The olefin is: